Relatively far Capital City Pairs compared to Country Centroids

Let D1 be the distance between 2 capital cities. Let D2 be the distance between the 2 corresponding country centroids (the geographical centers of the countries). For which pairs of capital cities is D1/D2 biggest?
Data from Portland State University (https://www.pdx.edu/econ/country-geography-data), for missing countries from CIA (https://www.cia.gov/library/publications/the-world-factbook/fields/2011.html)
The Country of Capital A comes before the Country of Capital B in alphabetical order
Quiz by scambigol
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Last updated: December 7, 2015
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First submittedDecember 7, 2015
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Average score52.5%
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D1 / D2
Capital City A
Capital City B
3.75
Bandar Seri Begawan
Kuala Lumpur
3.05
Lilongwe
Maputo
2.73
Ulaanbaatar
Moscow
2.35
Kinshasa
Kigali
2.30
Ashgabat
Tashkent
2.26
Phnom Penh
Hanoi
2.23
Bujumbura
Kinshasa
2.22
Libreville
Brazzaville
2.19
Bandar Seri Begawan
Jakarta
2.14
Algiers
Bamako
2.10
Buenos Aires
Santiago
2.06
Yerevan
Baku
2.05
Beijing
Moscow
2.04
Pyongyang
Moscow
1.94
Sarajevo
Zagreb
1.91
Havana
Kingston
1.91
Rome
San Marino
1.89
Jakarta
Kuala Lumpur
1.88
Malabo
Brazzaville
1.88
Tokyo
Moscow
+1
Level 67
Dec 7, 2015
Tokyo and Moscow?