Keep scrolling down for answers and more stats ...
1.
In chemistry, what is a spiro-compound?
A molecule that contains a bend or twist in its structure.
✓
A molecule that has at least two rings sharing only one common atom.
✓
A molecule that structurally resembles Spyro the dragon.
✓
A molecule containing two ring systems that are orthogonal to each other.
✓
2.
When was 1,3,3-trimethyl-spiropyran (the "standard" spiropyran) first synthesised?
It was synthesised in 1940 by German chemists R. Wizinger and H. Wenning.
3.
Which of the following statements is false?
UV light generally facilitates SP -> MC conversion.
✓
Spiropyrans are not found in nature.
✓
Spiropyrans generally exhibit negative photochromism.
✓
Spiropyrans do not exhibit solvatochromism.
✓
Spiropyrans generally exhibit positive photochromism: λmax(GS) < λmax(ES).
4.
What is a current commercial use of spiropyran-based materials?
Colour-changing swimwear.
✓
Electro-optic data storage.
✓
Colorimetric humidity sensors in museums/galleries.
✓
Photochromic sunglasses.
✓
5.
Why does our group study spiropyrans?
For use in photoresponsive MOFs.
✓
Because they're colourful and nice to look at.
✓
6.
What is a major advantage of spiropyrans vs other photoswitches, such as azobenzenes and diarylethenes?
Large change in dipole moment upon photoconversion.
✓
Higher thermal stability.
✓
More easily synthesised.
✓
Resistant to photobleaching.
✓
μ(SP) ~ 4 D, μ(MC) ~ 17 D. Therefore, vastly different physicochemical properties.